Automatic speech recognition (ASR) systems are commonly evaluated with word error rate (WER), yet many voice workflows depend on exact written values for identifiers, paths, and measured quantities. A transcript can appear fluent and achieve low WER while corrupting a value that a downstream system must parse, store, or execute. We introduce VoiceCodeBench, a benchmark for evaluating exact structured-token recovery in English ASR. It contains 300 human-recorded workplace segments spanning eight workflow domains and 1,482 audited target entities across 26 entity types, each with a canonical written form recoverable from the audio. Under a raw-audio-only protocol, systems receive audio bytes without additional context or metadata. Alongside WER, we evaluate Canonical Token/Entity Match (CTEM), Task Success Rate (TSR), and per-type exact recovery. Across 12 baseline ASR systems, lower WER generally corresponded to better structured-token recovery but did not fully determine it: Spearman correlations were -0.73 for both WER versus CTEM and WER versus TSR. The strongest baseline by TSR reached only 68.7%, leaving nearly one third of recordings with at least one unrecovered workflow-critical value. These results show that entity-sensitive metrics are needed to assess whether ASR output preserves exact values that production systems must parse, route, store, compare, or execute.

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