Sampling multiple responses improves language model reasoning, but uniform compute allocation is inefficient because easy questions are over-sampled while hard questions remain under-explored. We propose \textbf{Uncertainty-Aware Budget Allocation (UAB)}, a concave integer optimization framework that reallocates a fixed sampling budget using uncertainty estimated from the initial samples themselves. In Phase-1, every question receives a small fixed number of generations. Their answer disagreement, measured by vote entropy, provides a difficulty signal while these generations contribute to the final vote. In Phase-2, the remaining budget is allocated by a marginal-greedy algorithm that optimally solves a concave coverage-maximization surrogate, concentrating samples on questions whose initial answers disagree. Across five open-weight models (1.5B--27B parameters) and five reasoning benchmarks of varying difficulty, UAB improves average accuracy by $+2.3\%$ over uniform allocation, and achieves gains of up to $+5.5\%$ on individual benchmarks, with the largest gains in low-resource settings. Moreover, UAB meets the target budget exactly and requires no auxiliary model or additional LLM calls. Code is publicly available at https://github.com/manhitv/UAB.

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