Vision-language models (VLMs) used as robotic critics, reward generators, and failure detectors must understand how manipulation unfolds, not only whether it succeeds. Yet fine-grained process supervision is not readily available in a unified form, and existing evaluations do not systematically diagnose these abilities. We introduce Robo2Process, a trace-grounded framework for scalable construction of process-aware supervision from heterogeneous robotic execution data. It aligns visual observations with source-native signals and annotations, extracts local process units (LPUs), and generates structured QA supervision through task-specific sampling, deterministic label construction, and ambiguity filtering. We instantiate this framework as RoboProcessBench, a diagnostic benchmark with 12 question families spanning \emph{static monitoring} and \emph{dynamic reasoning}, and ProcessData, a corpus of 57,892 QA pairs across four data sources and 260 manipulation tasks, split into ProcessData-SFT and ProcessData-Eval. Evaluation of a broad suite of VLMs reveals uneven process understanding. Supervision from ProcessData-SFT improves \textit{Qwen2.5-VL-7B} and \textit{InternVL-3-8B} on local state, motion, progress, and primitive-aware cues. External evaluation on RoboRewardBench shows Robo2Process enables out-of-distribution process-aware reasoning abilities. Overall, Robo2Process provides a source-aware pipeline, diagnostic benchmark, and learnable substrate for process-aware understanding in robotic manipulation.

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