Open-vocabulary remote sensing segmentation has recently emerged as a promising paradigm that enables pixel-level recognition of arbitrary categories specified by natural language, including classes unseen during training. However, geospatial domain shifts caused by heterogeneous regions, spatial resolutions, and acquisition platforms weaken visual-text matching and limit cross-dataset generalization. Recent attempts have begun to incorporate auxiliary vision foundation models (VFMs), typically coupling their features with text embeddings as additional matching evidence. However, this strategy may introduce inconsistent matching signals while leaving the structure-sensitive representations of VFMs insufficiently exploited. We therefore propose GeoSeg-OV, which decouples auxiliary VFM features from visual-text matching and repurposes them as structural guidance for cost aggregation and decoding. GeoSeg-OV constructs an orientation-robust cost volume from multi-rotation CLIP features, while a frozen VFM extracts multi-scale structure-sensitive features in parallel. We propose Structure-Guided Aggregation (SGA), which integrates cost tokens and CLIP semantic guidance with VFM-derived pairwise structural biases for coherent spatial propagation, followed by text-conditioned class-wise reasoning. We further introduce Cost-Aware Decoding (CAD) to adaptively refine and fuse multi-scale semantic and structural guidance based on the current decoder context. On the global High-Resolution Land Cover (HRLC) benchmark spanning seven datasets across six continents, GeoSeg-OV outperforms the state-of-the-art by +2.5 and +2.7 average mIoU under two training settings. A large-scale zero-shot case study further demonstrates its generalization across geographic domains and category systems without target-domain annotations or retraining.

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