We prove the first quantum-classical separation for a sampling problem over a continuous domain. For a class of Gibbs states $p\propto e^{-βE}$ on the torus $\mathbb{T}^d$ with smooth ($s$-Gevrey) potential and barrier amplitude $α=e^{βΔ}$, where $Δ= \max E-\min E$, every classical algorithm querying the value, gradient, or any higher-order derivatives of the log-density requires $Ω(α)$ queries to sample at constant accuracy in total variation distance, while a quantum algorithm based on quantum singular value thresholding and temperature annealing samples with $\tilde{O}\left(\sqrtα\right)$ queries to an oracle for the gradient. The advantage is quadratic in the barrier amplitude, which becomes exponential in the dimension, $e^{Ω(d)}$, at low temperature. The classical bound is information-theoretic, holding for every classical algorithm with query access to the Gibbs potential and its derivatives at any order.

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