Spiking neural networks (SNNs) enable sparse and event-driven computation, but their low-bit deployment remains incomplete because recurrent membrane states are commonly retained in floating point even after weight quantization. Quantizing these states is challenging because their distributions differ across channels and from the preceding weights, while small perturbations near the firing threshold may alter spike decisions and accumulate over time. We propose PTQ4SNN, a membrane-aware post-training quantization framework that jointly quantizes weights and recurrent membrane states using only a small calibration set. First, a channel-wise Unified Scale Bridge constrains the membrane scale as s_mem,c = s_w,c * 2^k_c, adapting to membrane distributions while enabling shift-compatible scale conversion. Second, Mixed-Precision Bit Allocation assigns 2/4/8-bit precision to membrane channels according to firing activity and quantization sensitivity under an average-bit budget. The framework operates on reusable projection-LIF pairs and supports both convolutional SNNs and spike-driven Transformers without backbone retraining. Experiments on static and event-based classification and semantic segmentation show that PTQ4SNN effectively preserves model accuracy under W4 quantization and approximately 4-bit membrane precision.

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