We establish unbounded two-use Holevo additivity gaps in finite dimensions. For each sufficiently large fixed integer $K$ and all sufficiently large $n$, we construct channels $T_n$ with output dimension $K^n$, input dimension $\exp(Θ_K(n^2))$, and \[ χ(T_n^{\otimes2})-2χ(T_n) \ge n\left[\frac{\log_2K}{K}-2\log_2(1+9/K)\right]-O(1/n). \] The gap is linear in output qubits, with an explicit quadratic input-qubit cost and an explicit threshold on $n$. We also obtain channels whose single-use Holevo quantity tends to zero while their two-use Holevo information, and hence classical capacity, diverges. The channels arise from structured tensor products of the complementary mixed-unitary channels used in Collins's free-probabilistic proof. We establish minimum-output-entropy gaps by combining Collins--Youn's product-group Haagerup inequality with Bordenave--Collins's quantitative strong-convergence estimates. We also provide a Lean certificate for our proofs.

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