Portuguese Information Retrieval (IR) lacks public datasets, and relevance assessment for specialized collections remains costly. While Large Language Models (LLMs) increasingly support relevance assessment, their reliability in non-English specialized domains remains unclear. We introduce NormasTCU (https://huggingface.co/datasets/LeandroRibeiro/NormasTCU), a Brazilian Portuguese IR dataset with 14,469 legal documents, 46 queries, and 3,048 human judgments over 812 query-document pairs. Using NormasTCU, we evaluated LLM-as-a-judge for relevance assessment by prompting three models with two prompt techniques to grade these pairs. We then compared the rankings of 15 IR systems derived from LLM-generated and human reference qrels. LLMs consistently showed a positive scoring bias (mean absolute error: 0.46--0.66 on a 0-2 scale). Furthermore, pair-level agreement with human judgments achieved only fair to moderate levels, with Cohen's kappa ranging from 0.32 to 0.53. Despite this bias, LLM-generated judgments often yielded highly similar system rankings for nDCG@10 and MRR (observed Kendall's tau greater than or equal 0.90, although the bootstrap confidence intervals did not always remain above this threshold), but were less reliable for P@10 and R@10. Notably, LLM-based rankings were sometimes more strongly correlated with the reference ranking than individual human annotations were. As a practical implication, our results suggest that LLMs could effectively support scalable relevance assessment in specialized Portuguese corpora when evaluated using nDCG or MRR (rank-aware metrics), but they should be avoided when relying on precision or recall.

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