While AI-generated content (AIGC) models have achieved remarkable success in generating photorealistic videos, their potential to support visual, story-driven learning in education remains largely untapped. To close this gap, we present EduAIGV-1k, the first benchmark dataset and evaluation framework dedicated to assessing the quality of AI-generated videos (AIGVs) designed to teach foundational math concepts, such as numbers and geometry, to young learners. EduAIGV-1k contains 1,130 short videos produced by ten state-of-the-art text-to-video (T2V) models using 113 pedagogy-oriented prompts. Each video is accompanied by rich, fine-grained annotations along two complementary axes: (1) Perceptual quality, disentangled into spatial and temporal fidelity, and (2) Prompt alignment, labeled at the word-level and sentence-level to quantify the degree to which each mathematical concept in the prompt is accurately grounded in the generated video. These fine-grained annotations transform each video into a multi-dimensional, interpretable supervision signal, far beyond a single quality score. Leveraging this dense feedback, we introduce EduVQA for both perceptual and alignment quality assessment of AIGVs. In particular, we propose a Structured 2D Mixture-of-Experts (S2D-MoE) module, which enhances the dependency between overall quality and each sub-dimension by shared experts and dynamic 2D gating matrix. Extensive experiments show our EduVQA consistently outperforms existing VQA baselines. Both our dataset and code will be publicly available.

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