Large language models (LLMs) are increasingly applied to resume optimization for applicant tracking systems, introducing hallucination failures distinct from general text generation: anachronistic technology injection, cross-domain terminology contamination, structural mutation, and content fabrication. We present Grounded Optimization, a five-layer framework combining temporal context validation, deterministic contamination detection, structural invariant enforcement, prompt-level grounding, and an evaluator agent. In ablation experiments across three LLMs, four temperature settings, and six layer configurations on 25 synthetic resumes spanning 14 industries, undefended baselines produce 2.48-5.36 detected hallucinations per resume. Among detectors independent of the active defenses, temporal hallucinations are reduced by 50-95% across all conditions; overall detected hallucination rate falls to 0.04-0.24. Prompt-level grounding alone achieves zero detected hallucinations at low temperature with a capable instruction-following model; higher temperatures and weaker models reveal the need for the deterministic layers as a complement. We release the contamination taxonomy, evaluation code, and raw data.

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