Open-world geo-localization requires models to reason over ambiguous visual cues through multi-step reasoning and external knowledge grounding. While recent large vision-language models exhibit strong multimodal reasoning capabilities, existing approaches still suffer from perceptual hallucination and context drift due to the lack of explicit evidence-grounded verification. In this work, we reformulate geo-localization as a human-like perceive-then-verify reasoning problem and propose GeoPAVE (Geo-localization Perception-and-Verification-Engine), a bi-level agentic framework that contains perception-based hypothesis generation via single-pass rollouts and verification-based evidence grounding for decision actions: support, refute, and refine. To support rigorous evaluation, we further introduce PAVED, a novel dataset derived from real-world user check-in data, equipped with comprehensive reasoning trajectories featuring multi-hop queries, multi-round tool invocations, and structured perception-verification traces. The dataset and code are available at https://github.com/Arandinglv/GeoPAVE.

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