In this paper, we investigate the performance of ambient backscatter communication non-orthogonal multiple access (AmBC-NOMA)-assisted short packet communication for high-mobility vehicle-to-everything transmissions. In the proposed system, a roadside unit (RSU) transmits a superimposed signal to a typical NOMA user pair. Simultaneously, the backscatter device (BD) transmits its own signal towards the user pair by reflecting and modulating the RSU's superimposed signals. Due to vehicles' mobility, we consider realistic assumptions of time-selective fading and channel estimation errors. Theoretical expressions for the average block error rates (BLERs) of both users are derived. Furthermore, analysis and insights on transmit signal-to-noise ratio, vehicles' mobility, imperfect channel estimation, the reflection efficiency at the BD, and blocklength are provided. Numerical results validate the theoretical findings and reveal that the AmBC-NOMA system outperforms its orthogonal multiple access counterpart in terms of BLER performance.

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