This paper investigates the power control problem in wireless networks by repurposing pre-trained large language models (LLMs) as relational reasoning backbones. In hyper-connected interference environments, traditional optimization methods face high computational cost, while standard message passing neural networks suffer from aggregation bottlenecks that can obscure critical high-interference structures. In response, we propose PC-LLM, a physics-informed framework that augments a pre-trained Transformer with an interference-aware attention bias. The proposed bias tuning mechanism injects the physical channel gain matrix directly into the self-attention logits, enabling explicit fusion of wireless topology with pre-trained relational priors without retraining the backbone from scratch. Extensive experiments demonstrate that PC-LLM consistently outperforms both traditional optimization methods and state-of-the-art graph neural network baselines, while exhibiting exceptional zero-shot generalization to unseen environments. We further observe a structural-semantic decoupling phenomenon: Topology-relevant relational reasoning is concentrated in shallow layers, whereas deeper layers encode task-irrelevant semantic noise. Motivated by this finding, we develop a lightweight adaptation strategy that reduces model depth by 50\%, significantly lowering inference cost while preserving state-of-the-art spectral efficiency.

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