We introduce GeoOutageBench, a benchmark for assessing LLM-based geospatiotemporal KGQA for multimodal outage and resilience analysis. Unlike existing KGQA benchmarks for Web knowledge, GeoOutageBench considers a spatiotemporal KG that integrates visual, textual, and structured data from outage records, remote sensing, weather observations, storm and power events, geographic entities, and domain ontologies. It provides a competency query taxonomy at different difficulty levels from spatiotemporal containment and proximity, spatiotemporal co-occurrence analysis, multimodal evidence, to hypothetical evaluation. Over multimodal KG and query classes, GeoOutageBench provides user-configurable evaluation of three important, highly coherent yet less studied tasks: (1) LLMs' understanding for ambiguous geospatiotemporal questions in terms of NL to SPARQL interpretation, (2) query-driven assessment of ontology utility, and (3) answer accuracy of multimodal KGQA retrieval. GeoOutageBench provides a design principle and foundation for assessing LLM-KG systems that support real-world infrastructure resilience analysis. Our benchmark, source code, data, results, and other documentation are available at https://github.com/UCF-SAGE/GeoOutageBench.

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