On-policy distillation (OPD) has emerged as an effective post-training paradigm for language models, with recent efforts extending it to block diffusion language models (BDLMs). However, existing studies focus almost exclusively on small block sizes, leaving distillation into student models with larger blocks underexplored. In this work, we investigate this regime and reveal two critical optimization biases that induce severe training instability. First, mismatched block boundaries between teacher and student cause \textbf{\textit{context misalignment}}, providing distorted supervisory signals that misguide student decoding. Second, even under aligned contexts, an \textbf{\textit{intrinsic optimization bias}} in OPD, where the student tends to rapidly absorb high-support signals while lagging on low-support updates, drives a premature confidence surge that traps weaker students in catastrophic overconfidence collapse. To resolve these, we propose \mbox{\textbf{Un-OPD}}, an unbiased on-policy distillation framework with two novelties for stabilizing BDLM training. First, Un-OPD introduces a boundary-aware step filtering strategy that eliminates context-misaligned decoding steps. Second, Un-OPD proposes moderating optimization intensity at high-support positions via a support-rebalanced confidence calibration, thereby bypassing overconfidence collapse. Beyond stability, we also introduce a rollout reuse mechanism to reduce rollout generation overhead. Extensive experiments on math reasoning and code generation benchmarks show that Un-OPD consistently stabilizes training and delivers superior performance while reducing wall-clock training time by approximately half.

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