Transparent surfaces are ubiquitous in built environments, yet they remain a persistent failure case for robotic perception. RGB cameras perceive the background behind glass rather than the surface itself, while depth sensors such as LiDAR, time-of-flight, and RGB-D often return invalid or background measurements in transparent regions. As a result, systems that rely solely on optical sensing may misinterpret glass walls, doors, or mirrors as free space, compromising safe and reliable navigation. Existing glass segmentation approaches address this by learning visual cues such as reflections, boundaries, and semantic context from RGB images. While effective under favourable lighting and viewing conditions, these cues degrade in low-light environments, under glare, or when glass surfaces are featureless or partially occluded. In this work, we propose a multimodal framework that fuses millimetre-wave radar with RGB-D sensing for real-time transparent surface segmentation. Radar reflects strongly off glass surfaces, providing a geometric cue that remains reliable precisely where vision and depth fail. We exploit this cross-modal inconsistency to generate a radar-guided spatial prior, which is integrated into a lightweight transformer-based segmentation network, GlassFormer, via cross-modal attention. We report results on a mixed-condition test split covering all scene types and a dedicated low-light split designed to stress vision-only methods. GlassFormer achieves 0.88 mIoU on the mixed split, and 0.59 mIoU on the low light split, demonstrating substantial robustness gains over vision-only baselines while maintaining real-time performance on resource-constrained platforms.

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