With the rapid development of aerospace technology and the large-scale deployment of low Earth orbit (LEO) constellations, the risk of orbital collisions has increased, creating a growing demand for reliable observations of satellite maneuvers. However, public datasets containing real maneuver records remain scarce. We present MAD-LEO, a Maneuver-Annotated orbital Dataset for LEO satellites. The mission-reported subset contains 1,134 maneuver events from eleven geodetic and altimetry satellites spanning 1992 to 2026, with labels taken directly from mission-published maneuver histories. Each event is checked against two-line element (TLE) data, precise orbit products, and satellite laser ranging (SLR) observations, with evidence tiers assigned according to data availability. The operational subset pairs operator-published ephemerides for 6,785 Starlink satellites with cataloged TLE records over a continuous 107-hour period. Technical validation across seven machine-readable experiment suites confirms the cross-source consistency of the labels and the evidence products.

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