Evaluations of LLM-assisted qualitative coding almost universally measure model performance as agreement with human coders, a practice that presumes human coding is the standard to approximate. This study provides empirical evidence that the presumption fails in ways agreement metrics cannot detect. Five LLM systems and three trained human coders independently applied a 72-item hierarchical codebook to 2,560 educator messages from a K-12 AI platform. Beyond conventional agreement analysis, an independent domain expert judged 855 pairwise comparisons of code sets blind to source, treating human and machine sources symmetrically. The two evaluation approaches diverge in both directions. Human-LLM agreement (mean Jaccard 0.30) falls well below human-human agreement (0.52), which standard practice would read as inferior LLM coding, yet the blind verifier preferred human and LLM coding at indistinguishable rates (51.5% vs. 48.5%, p = 0.537), and a Bradley-Terry ranking placed two LLMs above two of three human coders. For several substantive codes, human consensus encoded shared bias that the verifier rejected in favor of the LLM interpretation. Agreement-based evaluation is therefore insufficient for automation decisions, and the study demonstrates a transferable verification protocol and a code-level division-of-labor framework.

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