Understanding facial behaviour in video requires answering three fundamental questions: when a key facial expression occurs, where the model attends on the face at that moment, and why that evidence is necessary rather than merely correlated. Today's multimodal large language models (MLLMs) can label and describe video, but they rarely provide faithful explanations, especially for small facial movements that change over time. We present VideoFace-X-LLM, a framework for explainable facial video understanding comprising two key components. First, we introduce ExplainFace, a weakly supervised video-text corpus for facial behaviour understanding, automatically constructed from CelebV-HQ videos and validated through human evaluation and a two-model audit (at most 2.3% contradictions), demonstrating consistent gains across two backbone architectures. Second, H-TCC (Hierarchical Temporal Spatial Causal Concepts), which finds the key temporal moments (When), the facial regions (Where), and verifies its causal necessity (Why) through targeted occlusion. Fine-tuning on ExplainFace raises appearance Macro F1 from 19.48% to 32.87% (+13.39), with gains of +4.38 on actions, +6.77 on temporal emotion, and +11.84 F1 on deepfake detection. We also measure the explanations pointing lift, face/edge lift, stability, an Adebayo sanity check, and a necessity test rather than only showing examples. Our models, code, and corpus are available on request for research use.

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