Astronomical maps made with different tracers are not expected to have identical morphology. Excitation, optical depth, chemistry, radiation, and ISM phase alter the response of a tracer, and the resulting differences can depend on both position and spatial scale. We propose scale-vector alignment, a scale-aware method based on Constrained Diffusion Decomposition (CDD). CDD decomposes an image into localized scale components; at each position, their amplitudes define a scale vector that describes how the measured intensity is distributed over spatial scale. We define the pixel-wise similarity $\Spix(x,y)$ as the normalized alignment of two local scale vectors. The normalization removes the overall amplitude, so $\Spix$ compares relative scale composition rather than absolute flux. We also define the scale-wise similarity $\Sscale(l)$ by comparing the two CDD component maps at each spatial scale. Spatial shifts are used to construct an empirical shifted reference distribution for $\Spix$. In Orion~A, the tracer with the highest similarity to the dust-derived column-density map changes from $^{12}$CO to $^{13}$CO to C$^{18}$O toward higher column density. In NGC~6334I(N), the line--continuum similarity decreases locally around the brightest compact structures, where radiative-transfer effects can alter the observed line morphology. In NGC~3627, CO is most similar to 21~$μ$m emission, and $\Sscale$ reaches its maximum at an intermediate sub-kpc scale. The method measures where two tracers have similar multiscale structure and at which scales their spatial distributions agree. The implementation is publicly available at https://github.com/meng-ke/Scale-Vector-Alignment.

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