Outcome-based reinforcement learning provides coarse supervision for long-horizon LLM agents: failed trajectories may contain correct steps, while successful trajectories can contain errors. Trajectory-level skills can also shift teacher preferences at unrelated steps, introducing off-target distillation signals. We introduce SCOPE, a framework for Selective Critical-Step On-Policy Self-Distillation. After a supervised warm-up, the policy analyzes its own trajectories, generates step-specific hindsight skills, and distills their guidance only at selected error steps. A bounded signed teacher-student coefficient stabilizes auxiliary updates while preserving positive reinforcement and negative correction. A success-relative pairwise length reward further encourages efficient task completion. Experiments on ALFWorld and WebShop demonstrate consistent improvements across multiple model backbones. With Qwen2.5-3B, SCOPE achieves 97.7% success on ALFWorld and 85.2% on WebShop, outperforming SEED by 5.9 and 6.3 percentage points, respectively. On unseen ALFWorld tasks, SCOPE reaches 89.6% success, improving over GRPO by 23.2 percentage points with 46.7% fewer interactions. Scaling to Qwen3-32B, SCOPE achieves 99.2% success on seen ALFWorld tasks and 94.0% on unseen tasks.

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