As Multimodal Large Language Models (MLLMs) evolve into sophisticated interactive assistants, their reliability depends not only on following instructions but also on validating them. We define Proactive Critique as the model's autonomous ability to identify, analyze and fix faulty user inputs without extra prompts. However, evaluations mainly test models under ideal circumstances or simple refusal behaviors, largely ignoring active error processing. To fill this gap, we propose MMPCBench, a comprehensive framework for evaluating MLLMs' proactive critique competence. It features a fine-grained taxonomy of 4 primary error types spanning 12 subcategories, ranging from cross-modal contradictions to missing visual premises. We adopt a hierarchical evaluation protocol to measure models' error detection, diagnosis and resolution performance, and apply alignment-aware metrics to assess the coherence between internal reasoning and final responses. Tests on 14 mainstream MLLMs show obvious weaknesses in proactive critique, especially in dealing with subtle visual anomalies. Notably, we identify a pervasive "consistency gap": reasoning models can often correctly identify and analyze errors during internal reasoning yet suppress these valid insights in final outputs to prioritize response compliance. The code and data is available at https://github.com/ALIENS32/MMPCBench.

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