AI is increasingly used to support decarbonization decisions across the built environment, yet the development, training, and use of AI consume energy and induce CO2e emissions. However, existing assessments often report physical-system savings while omitting AI-side emissions. Moreover, they rarely account for the mismatch between when AI costs occur and when decarbonization benefits materialize, which may be substantial for infrastructure-scale projects. To address these issues, we present a time-aware assessment framework that models avoided emissions and AI-induced emissions as discrete-time streams over a finite time horizon. In demonstrating this process, we seek to show that time-aware assessment can support temporal decision-making, identify cases in which accounting for time value of carbon can change preferred rankings relative to time-invariant totals, and explore how decisions may vary with slightly different governance priorities. Using four representative interventions with intentionally different temporal profiles (multi-project low-carbon concrete design support, AI-assisted construction logistics, agentic HVAC control, and predictive maintenance), we demonstrate how discounting can change preferred rankings relative to time-invariant totals and supports ranking sensitivity analysis, discounted payback screening, and break-even discount-rate analysis. We also provide decision guidelines that support go/no-go screening, timing decisions, and minimum "bang-for-your-buck" thresholds. Ultimately, this work contributes a lightweight framework for deciding whether and when to deploy AI-enabled interventions for decarbonization under explicit time preference.

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