How much phonological knowledge do language models (LMs) possess about Chinese characters, and how is this knowledge represented and used? We introduce PinyinBench, a controlled benchmark covering homophones, phonological features (initials, finals, and tones), and polyphonic characters. We investigate 17 text-only and multimodal LMs through three complementary approaches: behavioral evaluation, layer-wise probing, and activation steering. Behaviorally, models demonstrate substantial knowledge of initials and finals, with a frontier model (DS-v4-flash) scoring 90%+ in homophone judgment, when two characters share no phonological features. However, its accuracy drops sharply to 72% when two characters differ only in lexical tone. Probing reveals that tone is highly decodable from embeddings and improves modestly across layers, whereas segmental information starts less decodable and improves substantially with depth. Activation steering shows that segmental representations can systematically influence generation, while tone exhibits much weaker effects. Furthermore, audio-bearing training improves phonological decodability, including tone, without corresponding improvements in steering effectiveness. Together, these findings reveal distinct representational and functional profiles for segmental and tonal information, with tonal information much harder to access and manipulate, demonstrating the necessity for combined evaluation, probing, and causal intervention for understanding linguistic knowledge in LMs.

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