Multimodal Recommender Systems (MRSs) typically rely on a flawed "modality harmony" assumption, presuming that multimodal features are inherently beneficial and strictly aligned with users' collaborative interaction patterns. However, modality-topology conflicts are ubiquitous in real-world scenarios due to deceptive visual clickbaits and mismatched semantics. Blindly integrating these noisy modalities inevitably pollutes the pristine collaborative space, causing severe representation distortion. To address this, we propose Orthogonal purification and topology-guided MoE for conflict-aware multimodal Recommendation (OrthoRec). At its core, OrthoRec introduces Collaborative-Guided Orthogonal Purification (CGOP), which geometrically decouples multimodal features into directions parallel and orthogonal to a pure collaborative anchor. By adaptively truncating the orthogonal noise with an energy-preserving normalization, CGOP rectifies deceptive semantic directions while preserving the modality's intrinsic representation capacity. Furthermore, we design a Topology-Aware Routing Mixture-of-Experts (TAR-MoE). Guided by the collaborative topology, TAR-MoE employs decoupled sigmoid gating to break the zero-sum bottleneck of traditional softmax attention, autonomously determining the injection scale for each purified modality. Finally, a safe-SSL objective is introduced to dynamically penalize the forced contrastive alignment of contradictory pairs. Experiments on three real-world Amazon datasets show that OrthoRec consistently outperforms competitive recent baselines and exhibits improved robustness under modality noise and item sparsity.

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