Effectively scaling Reinforcement Learning (RL) is crucial for enhancing the reasoning and alignment of Large Language Models. The massive data and complex execution flows inherent in these tasks require a distributed architecture capable of efficient scaling. However, to simplify programming and dependency management, mainstream frameworks often rely on a centralized architecture where a single node dispatches both control and data. This inherent coupling creates significant communication bottlenecks, severely limiting system scalability and efficiency. We present DISTFLOW, a novel, fully distributed RL framework that adopts a multi-controller paradigm. By decoupling data transmission from control dispatch, DISTFLOW establishes a parallelism-aware, decentralized Data Coordinator that leverages local caching, load balancing, and asynchronous double buffer to minimize communication overhead and mitigate straggler effects. For control logic, it introduces a task scheduler built upon Directed Acyclic Graph (DAG) that facilitates fine-grained, independent execution. Experimental results demonstrate that DISTFLOW achieves near-linear scalability up to 512 GPUs and delivers up to a 2.63x throughput improvement over state-of-the-art (SOTA) frameworks. The source code is available at: https://github.com/sii-research/siiRL.

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