Mobile gas-sensing inspection requires a mobile platform to reliably reach ordered sampling poses. We present MIRA-PRM, a mission-informed probabilistic roadmap that combines geometry-, mission-flow-, and inspection-conditioned sampling with locally adaptive connectivity and evidence-gated refinement. Eight development campaigns comprising 142,448 planner runs evaluated mission scaling, repeated-query adaptation, finite node budgets, target distributions, local map repair, ablation, cross-family comparison, and parameter sensitivity. MIRA-PRM maintained 100% seed-level success as ordered targets increased from two to eight, and achieved 97.67% seed-level success under a 40-node ceiling, compared with 67.17% for PRM and 86.50% for PRM*. Local repair reduced event time by 79.9-81.9% and node additions by 90.8-94.3% relative to rebuilding. On a separate frozen holdout of 12 maps, 48 ordered missions, and three seeds per map-mission unit, MIRA-PRM produced 96/144 validated successes, versus 82/144 for PRM, 89/144 for PRM*, and 70/144 for LE-HG-PRM. On paired common-success runs, MIRA-PRM reduced wall time by 16.89% relative to PRM* and 81.01% relative to LE-HG-PRM, but was 52.23% slower than PRM; paths were 0.54-1.86% longer. All validated paths passed independent full-segment checks and clearance non-inferiority. The results support a reliability-oriented trade-off in structured simulations and motivate external-map and physical mobile-sensing validation.

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