As organizations increasingly deploy LLMs in sensitive domains such as legal, financial, and medical settings, ensuring alignment with internal organizational policies has become a priority. Existing content moderation frameworks remain largely confined to the safety domain and lack the robustness to capture nuanced organizational policies. LLM-as-a-judge and fine-tuning approaches, though flexible, introduce significant latency and training cost. To address these limitations, we frame policy violation detection as an out-of-distribution (OOD) problem in the model's activation space. We propose a training-free method that operates directly on the LLM internal representations, leveraging prior evidence that decision-relevant information is encoded within them. Inspired by whitening techniques, we derive policy-violation scores directly from normalized representations of LLM hidden activations. Our method requires only the policy text and a small number of illustrative samples, making it lightweight and easily deployable. We extensively evaluate our method across multiple LLMs and challenging policy benchmarks. It achieves up to 86.0% F1, outperforming both fine-tuned and LLM-as-a-judge baselines while requiring substantially less computation. Our code is publicly available at: https://github.com/FujitsuResearch/LLM-policy-violation-detection

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