In this paper, we study the problem of promptly detecting the presence of non-cooperative activity from one or more Reconfigurable Intelligent Surfaces (RISs) with unknown characteristics lying in the vicinity of a Multiple-Input Multiple-Output (MIMO) communication system using Orthogonal Frequency-Division Multiplexing (OFDM) transmissions. We first present a novel wideband channel model incorporating RISs as well as non-reconfigurable stationary surfaces, which captures both the effect of the RIS actuation time on the channel in the frequency domain as well as the difference between changing phase configurations during or among transmissions. Considering that RISs may operate under the coordination of a third-party system, and thus, may negatively impact the communication of the intended MIMO OFDM system, we present a novel RIS activity detection framework that is unaware of the distribution of the phase configuration of any of the non-cooperative RISs. In particular, capitalizing on the knowledge of the data distribution at the multi-antenna receiver, we design a novel online change point detection statistic that combines a deep support vector data description model with the scan $B$-test. The presented numerical investigations demonstrate the improved detection accuracy as well as decreased computational complexity of the proposed RIS detection approach over existing change point detection schemes.

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